Deuterium Oxide for OLEDs

Deuterium Oxide for OLEDs illustration

Deuterated organic molecules extending the operational lifetime of OLED displays

Organic light-emitting diodes (OLEDs) are extensively used in devices such as television and mobile phone screens. OLEDs are generally made of thin layers of organic molecules between two electrodes. The devices emit light when an electric current flows through them.

Until a few years ago, the biggest technical problem for OLEDs was the limited lifetime of the organic materials, typically half that of LCD, LED or PDP, as heat and oxidation generated during operation contribute to the instability of the chemicals. The problem was solved by deuterating some of the organic molecules incorporated in OLEDs, which increases the lifetime of the device by a factor of five to 20 without significantly affecting other properties of the device.

Another application of deuteration in this field is neutron reflectometry, which combined with the deuteration of specific molecular layers has become the key method for studying the morphology, diffusion, and interfacial behavior in organic thin-film semiconducting devices.

🔬 Why deuteration extends device life

Deuterated compounds demonstrate improved thermal stability due to the higher bond dissociation energy of C-D bonds compared to C-H bonds. Deuteration also mitigates chemical reactions with residual oxygen or moisture inside the device, providing an extra layer of durability against the photo-oxidative degradation that limits standard OLED lifespans.

5–20x longer lifetime
Neutron reflectometry
Improved thermal stability

Deuterated Reagents for Electronics

Catalog number Description
D009 Acetone-d6 (D, 99.5%) — ~25% sol. in D2O
D001 Benzene-d6 (D, 99%)
HPG-040 Carbon monoxide — CP 99.99%
HPG-045 Carbon monoxide — CP 99.995%
D007 Chloroform-d (D, 99.7%)
DLM-408DR Deuterium (D, 99.8%) (D2, 99.6% + HD, 0.4%)
DLM-408-HP Deuterium (D, 99.8%) CP 99.999%
DLM-408-4NHP Deuterium (D, 99.8%) CP 99.99%+
DLM-458DR Deuterium chloride (D, 99%)
DLM-3DR Deuterium chloride (D, 99.5%) — DCl 35% w/w solution in D2O
DLM-4DR-99.8 Deuterium oxide (D, 99.8%)
DLM-4DR Deuterium oxide (D, 99.9%)
DLM-10RG-PK Dimethyl sulfoxide-d6 (D, 99.9%)
DLM-24RG Methanol-d4 (D, 99.5%)
DLM-45DR Sodium deuteroxide (D, 99.5%) 40% in D2O
DLM-33DR Sulfuric acid-d2 (D, 99%) 96-98% in D2O
D005 Toluene-d8 (D, 99.5%)
DLM-46RG Trifluoroacetic acid-d (D, 99%)

References

  • Tsuji, H.; Mitsui, C.; Nakamura, E. 2014. The hydrogen/deuterium isotope effect of the host material on the lifetime of organic light-emitting diodes. ChemComm, 50(94), 14870–14872. PMID: 25325237

Technical Product Information